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#31
Han Zuilhof (born 1965) holds the Chair of Organic Chemistry at Wageningen University. His interests focus on surface-bound (bio-)organic chemistry and bionanotechnology. He obtained an MSc in Chemistry and MA in Philosophy from Leiden University (both highest honors). After a PhD in Organic Chemistry (Leiden University, 1994; highest honors), and postdoctoral work at the University of Rochester, NY, and Columbia University, he joined the faculty at Wageningen University. He has been a Professor of Organic Chemistry since 2007. He has written over 300 research papers,[1] and more than 10 patents. He is a Distinguished Adjunct Professor of Chemical Engineering at the King Abdulaziz University in Jeddah, Saudi Arabia, and a Perennial Distinguished Guest Professor of Molecular Science and Medicinal Chemistry at the School of Pharmaceutical Science and Technology (SPST) at Tianjin University, China. He serves/served on the Editorial Advisory Boards of Langmuir, Advanced Materials Interfaces and Applied Surface Science.

In 2016, he was appointed Senior Editor of Langmuir.[2] And in 2018, Han Zuilhof was elected as a "Fellow of the Royal Society of Chemistry (RSC) for his outstanding contributions to chemical science.[3][4]

He is a founder (2011) of a spin-off company Surfix, and co-founder (2013) of another, Biomarque.[5]
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#32
Michael Smith (born August 27, 1972) is a Canadian actor, screenwriter, comedian and musician born in New Glasgow, Nova Scotia, and raised in Thorburn. He is best known for his portrayal of Bubbles and co-writer of the cult classic television program, films and stage production Trailer Park Boys. He was also the guitarist for the Canadian rock band Sandbox. Smith earned a degree in English from St. Francis Xavier University in Antigonish, Nova Scotia.[1] For a short time in 2006, he was engaged to actress Nichole Hiltz.
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#33
U.S. Route 6 (US 6) in New York is a 77.85-mile (125.29 km) stretch of cross-country route that spans from the Pennsylvania state line at Port Jervis to the Connecticut state line east of Brewster. Near both ends it runs in close proximity to Interstate 84 (I-84), which otherwise takes a more northerly route through Downstate New York. US 6, meanwhile, skirts the northern fringe of the New York Metropolitan Area.

Except for a section concurrent with the expressway portion of New York State Route 17 (the future I-86) and another brief, similar stretch in Peekskill, US 6 is a two-lane road in New York. Two stretches are shared with US 202. It goes through three of New York's traffic circles, more than any other highway in the state, and is part of the only concurrency of three U.S. routes in the state.

US 6 is not as important a transportation artery in New York as it in some other states. The route does, however, pass through some of the region's more memorable scenery, particularly the Hudson Highlands in the form of Harriman and Bear Mountain state parks. It crosses the Hudson River at the historic Bear Mountain Bridge. Other highlights include the Shawangunk Ridge in the west and New York City's reservoirs in the east.
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#34
The New York Rangers are a professional ice hockey team based in New York City. They are members of the Metropolitan Division of the Eastern Conference of the National Hockey League (NHL). The team plays its home games at Madison Square Garden in the borough of Manhattan, an arena they share with the New York Knicks of the National Basketball Association (NBA). They are one of three NHL teams located in the New York metropolitan area; the others being the New Jersey Devils and New York Islanders.

Founded in 1926 by Tex Rickard, the Rangers are one of the Original Six teams that competed in the NHL before its 1967 expansion, along with the Boston Bruins, Chicago Blackhawks, Detroit Red Wings, Montreal Canadiens and Toronto Maple Leafs. The team attained success early on under the guidance of Lester Patrick, who coached a vibrant team containing Frank Boucher, Murray Murdoch, and Bun and Bill Cook to Stanley Cup glory in 1928,[3] making them the first NHL franchise in the United States to win the trophy. The team would then go onto win two additional Stanley Cups in 1933 and 1940.

Following this initial grace period, the franchise struggled between the 1940s and 1960s, whereby playoff appearances and success was infrequent. The team enjoyed a mini renaissance in the 1970s, where they made the Stanley Cup finals twice, albeit, losing to the Bruins in 1972 and the Canadiens in 1979. The Rangers subsequently embraced a rebuild for much of the 1980s and early 1990s, which eventually paid dividends, where the team, led by Mark Messier, Brian Leetch, Adam Graves, and Mike Richter, captured their fourth Stanley Cup in 1994.

The team was unable to duplicate that success in the years that followed, and entered into another period of mediocrity. They endured a franchise-record seven-year postseason drought from 1998 to 2005, and languished for the majority of the 2000s before enjoying another period of prosperity after the 2004–05 NHL Lockout. Upon the arrival of goaltender Henrik Lundqvist, the Rangers missed the playoffs just once between 2006 and 2017. They reached the Stanley Cup Finals in 2014, falling to the Los Angeles Kings in five games. They have since entered into another period of rebuilding.[4]

Several former members of the Rangers have been inducted into the Hockey Hall of Fame, four of whom—Buddy O'Connor, Chuck Rayner, Andy Bathgate, and Messier—have won the Hart Memorial Trophy while playing for the team.
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#35
A resorcinarene (also resorcarene or calix[4]resorcinarene) is a macrocycle, or a cyclic oligomer, based on the condensation of resorcinol (1,3-dihydroxybenzene) and an aldehyde. Resorcinarenes are a type of calixarene. Other types of resorcinarenes include the related pyrogallolarenes and octahydroxypyridines, derived from pyrogallol and 2,6-dihydroxypyridine, respectively.

Resorcinarenes interact with other molecules forming a host–guest complex.[1] Resorcinarenes and pyrogallolarenes self-assemble into larger supramolecular structures. Both in the crystalline state and in organic solvents, six resorcinarene molecules are known to form hexamers with an internal volume of around one cubic nanometer (nanocapsules) and shapes similar to the Archimedean solids.[2] Hydrogen bonds appear to hold the assembly together. A number of solvent or other molecules reside inside.[3] The resorcinarene is also the basic structural unit for other molecular recognition scaffolds, typically formed by bridging the phenolic oxygens with alkyl or aromatic spacers.[4] A number of molecular structures are based on this macrocycle, namely cavitands and carcerands.
Synthesis
The resorcinarene macrocycle is typically prepared by condensation of resorcinol and an aldehyde in concentrated acid solution.[5][6] Recrystallization typically gives the desired isomer in quite pure form. However, for certain aldehydes, the reaction conditions lead to significant by-products. Therefore, alternative condensation conditions have been developed, including the use of Lewis acid catalysts.
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#36
Sneezing powder is a group of powders or powder-like substances that induce sneezing when someone is exposed to them. This is usually done as a practical joke or prank to an unsuspecting victim.

Sneezing powders containing Veratrum album alkaloids have been linked to poisoning, including upset stomach, fainting, slowed heart rate and low blood pressure.[1] Children are especially vulnerable.[2]

An example of a sternutatory (sneeze-inducing) agent is helenalin (the acetate is called angustibalin). The plant containing this chamissonolid is actually eponymously called sneezeweed.
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#37
Zygmunt Białostocki (15 August 1897 – c. 1942)[1] was a Polish Jewish musician. He composed many popular Polish pre-war songs, and worked as conductor and a première pianist in Warsaw between the World Wars.

Białostocki was born in Białystok, Poland. Between 1925–1930 he worked as music director and conductor in the Municipal Theatre in Łódź. Later he moved to Warsaw, where he worked in “revue-theaters” and cabarets (within what is known in Yiddish as kleynkunst), including Perskie Oko, Morskie Oko, Nowy Momus, and Nowy Ananas.[1]

He worked with the lyricist Zenon Friedwald (Zenon Frivald-Vardan). His song M’ken nisht tsvingen tsu keyn libe was popularized by the film actor and singer Eugeniusz Bodo in the Polish version called Nie można kogoś zmuszać do miłości. His tango Rebeka, built on Chasidic motifs and sung by Chasidic Jews[2] as zmiros was popular in nightclubs, coffee houses and restaurants across Warsaw between the wars. The lyrics is by Andrzej Włast; the song was first recorded by Zofia Terne (1932) and premiered at the Morskie Oko cabaret by Dora Kalinówna.[1]

In 1932 he was the music director and composer of the score for Biała trucizna (White Venom) movie.[3][4] In 1933 he worked as accompanist in the Warsaw Nowy Momus and Oasis cabarets, in the Warsaw-Prague Perskie Oko cabaret and in the Warsaw Nowy Ananas theater. His musical comedy called Miłość i złoto (Love and gold), written with Józef Haftman, opened in December 1933 at the Teatr 8:30.[5]

Apart from Rebeka, Białostocki's other szlagiery (hits) included:

- foxtrots: Ach, te Rumunki, Katiusza, Andriusza, Ecie-pecie (lyrics by himself);

- tangos: Jesienne marzenia, Andrusowskie tango, Pomalutku, po cichutku (lyrics by Andrzej Włast), Szczęście trzeba rwać jak świeże wiśnie and Zoboth (lyrics by W. Jastrzębiec).[6]

and Choć goło lecz wesoło (lyrics by Alexander Jellin), Nasze kawalerskie, Noc jesienna (lyrics by Zbigniew Drabik Argus, 1936), Na dnie serca, Nie można zmuszać do miłości, Pieśń o matce (Song about mother) (lyrics by Tadeusz Zeromski and Jerzy Wrzos, sung by Stefan Witas, 1933),

His wife Sofia was also a composer.

After the German invasion on Poland in 1939 the Białostockis were forced to live in German-ordered ghetto in Warsaw. They are mentioned about in Stanisław Adler's Warsaw ghetto memoir.

Zygmunt Białostocki was murdered by Germans during the liquidation of the Warsaw ghetto, most probably in 1942.[6]
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#38
Curtis James Jackson III (born July 6, 1975),[4] known professionally as 50 Cent, is an American singer, songwriter, rapper, actor, television producer, entrepreneur and investor. Born in the South Jamaica neighborhood of the borough of Queens, Jackson began selling drugs at age twelve during the 1980s crack epidemic. He later began pursuing a musical career and in 2000 he produced Power of the Dollar for Columbia Records, but days before the planned release he was shot and the album was never released. In 2002, after Jackson released the compilation album Guess Who's Back?, he was discovered by Eminem and signed to Shady Records, under the aegis of Dr. Dre's Aftermath Entertainment and Interscope Records.

With the aid of Eminem and Dr. Dre (who produced his first major-label album, Get Rich or Die Tryin'), Jackson became one of the world's best selling rappers and rose to prominence with East Coast hip hop group G-Unit (which he leads de facto). In 2003, he founded G-Unit Records, signing his G-Unit associates Young Buck, Lloyd Banks and Tony Yayo. Jackson had similar commercial and critical success with his second album, The Massacre, which was released in 2005. He released his fifth studio album, Animal Ambition, in 2014 and as of 2019 is working on his sixth studio album, Street King Immortal. He executive produces and stars in the show Power, which airs on Starz.[5]

During his career Jackson has sold over 30 million albums worldwide and won several awards, including a Grammy Award, thirteen Billboard Music Awards, six World Music Awards, three American Music Awards and four BET Awards.[6] He has pursued an acting career, appearing in the semi-autobiographical film Get Rich or Die Tryin' (2005), the Iraq War film Home of the Brave (2006) and Righteous Kill (2008). 50 Cent was ranked the sixth-best artist of the 2000s and the third-best rapper (behind Eminem and Nelly) by Billboard.[7] Rolling Stone consider Get Rich or Die Tryin' and "In da Club" to be in their lists of "100 Best albums of the 2000s" and "100 Best songs of the 2000s" at numbers 37 and 13 respectively.[8][9]
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#39
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